Imidazoles. II. A General Synthesis for 1-Hydroxyimidazoles
نویسندگان
چکیده
منابع مشابه
A novel Zn-catalyzed hydroamination of propargylamides: a general synthesis of di- and tri-substituted imidazoles.
Starting from commercially available amines and propargylamides a variety of substituted imidazoles were synthesized via a novel hydroamination-cyclization sequence. The target compounds are obtained in good to excellent yields in the presence of catalytic amounts of zinc triflate.
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To be fairly general and catalyst is easily separated by magnetic devices and can be reused without any apparent loss of activity for the reaction. Fe3O4 nanoparticles were prepared by chemical coprecipitation method and was found to be a mild and effective catalyst for the efficient, one-pot, three-component synthesis of 2,4,5-trisubstituted imidazoles at room temperature under ultrasound irra...
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Twenty-eight 1-ethyland l-p ropyl-5-substitu ted imidazoles were synthesized and their bleaching activity was evaluated by using the lettuce seedling test. 5-Phenyl1-propylimidazole (1) caused distinct chlorosis, while none o f the com pounds with various alkenyl groups at the 5-position o f the im idazole ring showed this bleaching activity. In troduction o f a brom o, chloro, fluoro, methyl o...
متن کاملMagnetic Fe3O4 nanoparticles as a highly efficient catalyst for the synthesis of imidazoles under ultrasound irradiation
To be fairly general and catalyst is easily separated by magnetic devices and can be reused without any apparent loss of activity for the reaction. Fe3O4 nanoparticles were prepared by chemical coprecipitation method and was found to be a mild and effective catalyst for the efficient, one-pot, three-component synthesis of 2,4,5-trisubstituted imidazoles at room temperature under ultrasound irra...
متن کاملRegioselective synthesis of 1,4-disubstituted imidazoles.
A short and efficient synthesis of 1,4-disubstituted imidazoles has been developed which provides the desired products with complete regioselectivity. This protocol allows preparation of compounds which are challenging to prepare by current literature methods in a regioselective fashion, a sterically and electronically diverse range of N-substituents being accessible. The sequence involves an u...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1969
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.42.3204